You can remove players from groups.
Procedure
In Setup mode, in the Players panel, remove players from groups in any of the following ways:
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Select multiple players, then click and drag them out of the group.
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Select one player, then click Player Settings
in the action bar and choose Remove Player from Group. You can also right-click players and choose this option from the context menu.
Result
The players are removed from their groups but remain in the project as individual players.